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Man I feel like your my older brother,
As your older brother, let me learn you English.
YOUR = Something that belongs to you. Possessive.
YOU'RE = A contraction for YOU ARE.
In the sentence you posted above, the correct word should have been "you're," since you were actually saying "Man, (I added the comma) I feel like you are my older brother.
Good luck to you little bro.
Rick