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Yes 5Star will take the Direct Express card. Using the card account number and getting the bank routing number for other cards will generally not work, unless it s a Net Spend card (sometimes). With other cards the draft will be returned (even if you get the account and routing number) because the account is "non-transactional," meaning that you can use the routing and account number for direct deposits, but not for EFT payments.
You didn't read my question right. I know 5 Star takes Direct Express, I use them. I said aren't there companies that take credit cards BUT WILL NOT take direct express. Monumental was one when they took credit cards but not direct express. Wonder what makes direct express different that they wouldn't take it even though it had the Mastercard Logo and can be used at retailers that take Mastercard.